Journal
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
Volume 92, Issue 1, Pages 249-252Publisher
WILEY
DOI: 10.1111/j.1551-2916.2008.02847.x
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Funding
- National Science Foundation [DMR-0409588]
- Materials World Network [DMR-0602975]
- Direct For Mathematical & Physical Scien
- Division Of Physics [849416] Funding Source: National Science Foundation
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We have investigated the evolution of the structure of nano-macro porous CaO-Na2O-P2O5-SiO2 bioactive glass-ceramics by Fourier transform infrared (FTIR) and Raman spectroscopies, and X-ray diffraction (XRD). A controlled devitrification, followed by a chemical leaching treatment is used to produce a multimodal distribution of nano/macro pores that are expected to improve cell attachment. Data show that the leaching process removes the sodium- and calcium-containing crystalline phases that are formed during the ceramming heat treatment. The primary Si-O peaks in the infrared spectra blue shift with leaching, indicating that the sample becomes SiO2 rich. In parallel, the fraction of nonbridging oxygen decreases. These results suggest a restructuring of the glass network far below the glass transition temperature. The stresses from leaching, capillary forces, and subsequent restructuring develop and grow, eventually producing cracks in the sample.
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