Journal
JOURNAL OF SYNCHROTRON RADIATION
Volume 17, Issue -, Pages 273-279Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S0909049509054910
Keywords
two-dimensional spectroscopy; QEXAFS; UV/Vis; in operando
Categories
Funding
- DFG [SFB 706]
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A novel experimental set-up for in operando studies of homogeneous catalyzed reactions under laboratory conditions has been developed and tested. It combines time-resolved X-ray absorption spectroscopy with UV/Vis spectroscopy. The reaction solution is stirred in a vessel and pumped in a circle by a peristaltic free gear-wheel through a measurement cell. The X-ray and UV/Vis beams probe the same sample volume of the cell orthogonally. Reactants can be added to the reaction mixture in the course of the measurements and a defined gas atmosphere can be adjusted up to a pressure of 10 bar. The in situ reduction of cerium(IV) ammonium nitrate to cerium(III) by isopropanol is studied as a test reaction with quick-XANES and UV/Vis measurements with a time resolution of 60 s and 1 s, respectively.
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