4.2 Article Proceedings Paper

X-ray magnetic spectroscopy at high pressure: performance of SPring-8 BL39XU

Journal

JOURNAL OF SYNCHROTRON RADIATION
Volume 16, Issue -, Pages 730-736

Publisher

INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S0909049509034700

Keywords

X-ray magnetic circular dichroism; multiple extreme conditions; high pressure; diamond anvil cell; in situ pressure calibration; Mn3GaC; ErCo2

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An X-ray magnetic circular dichroism experiment under multiple extreme conditions, 2 <= T <= 300 K, H <= 10 T and P <= 50 GPa, has been achieved at SPring-8 BL39XU. A combination of the high-brilliant X-ray beam and a helicity-controlled technique enabled the dichroic signal to be recorded with high accuracy. The performance is shown by the outcome of pressure-induced ferromagnetism in Mn3GaC and the pressure-suppressed Co moment in ErCo2. Two technical developments, a tiny diamond anvil cell inserted into a superconducting magnet and in situ pressure calibration using 90 degrees Bragg diffraction from a NaCl marker, are also presented. X-ray magnetic spectroscopy under multiple extreme conditions is now opening a new approach to materials science.

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