100 ps time-resolved solution scattering utilizing a wide-bandwidth X-ray beam from multilayer optics

100 ps time-resolved X-ray solution-scattering capabilities have been developed using multilayer optics at the beamline NW14A, Photon Factory Advanced Ring, KEK. X-ray pulses with an energy bandwidth of Delta E/E = 1-5% are generated by reflecting X-ray pulses (Delta E/E = 15%) through multilayer optics, made of W/B4C or depth-graded Ru/C on silicon substrate. This tailor-made wide-bandwidth X-ray pulse provides high-quality solution-scattering data for obtaining photo-induced molecular reaction dynamics. The time-resolved solution scattering of CH2I2 in methanol is demonstrated as a typical example.