4.0 Article

Self-propagating high-temperature synthesis of boron phosphide

Journal

JOURNAL OF SUPERHARD MATERIALS
Volume 35, Issue 6, Pages 415-417

Publisher

ALLERTON PRESS INC
DOI: 10.3103/S1063457613060105

Keywords

boron phosphide; synthesis; high temperature; high pressure; hardness

Funding

  1. Agence Nationale de la Recherche [ANR-2011-BS08-018]

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A new method of producing boron phosphide (BP) submicron powders by a self-propagating high-temperature reaction between boron phosphate and magnesium in the presence of an inert diluent (sodium chloride) has been proposed. Bulk polycrystalline BP with microhardness of H (V) = 28(2) GPa has been prepared by sintering the above powders at 7.7 GPa and 2600 K.

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