Journal
JOURNAL OF SUPERCRITICAL FLUIDS
Volume 50, Issue 1, Pages 46-53Publisher
ELSEVIER
DOI: 10.1016/j.supflu.2009.03.008
Keywords
Diethyl carbonate; Diethyl ether; Supercritical carbon dioxide; Ethanol; Potassium carbonate; One-pot process; Two-step reaction; Hybrid carbonate
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Carbon dioxide sequestration was studied by synthesizing diethyl carbonate (DEC) from ethanol and CO2 under supercritical conditions in the presence of potassium carbonate as a base. The co-reagent was ethyl iodide or a concentrated strong acid. This sequestration reaction occurs in two steps which were studied, separately and in a one-pot reaction. An organic-inorganic carbonate hybrid, potassium ethyl carbonate (PEC) is generated at the end of the first step. This intermediate was characterized and was found to be a target molecule for CO2 capture. Different co-reactants, such as ethyl iodide and concentrated strong Bronsted acid, were compared in the second step and used to investigate the reactivity of the hybrid. With ethyl iodide as the co-reactant, one-pot DEC synthesis gave higher yields (46%) than two-step production. The supercritical CO2 acts as a swelling solvent and compatibilizing agent in the reaction medium, favoring interactions between ethanol and CO2 and between PEC and ethyl iodide. The use of a phase transfer catalyst (PTC) increased DEC production (yield 51%) without increasing the amount of diethyl ether (DEE) produced as a by-product (yield 2%). (C) 2009 Elsevier B.V. All rights reserved.
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