4.1 Article

Direct synthesis of sulfonyl azides from sulfonic acids

Journal

JOURNAL OF SULFUR CHEMISTRY
Volume 35, Issue 2, Pages 119-127

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/17415993.2013.801476

Keywords

triphenylphosphine; trichloroisocyanuric acid; sulfonic acid; sulfonyl azide; sodium azide

Funding

  1. Ferdowsi University of Mashhad Research Council [p/3/20220]

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A one-pot process for the synthesis of various sulfonyl azides (RSO2N3) by treating sulfonic acids with triphenylphosphine/trichloroisocyanuric acid/sodium azide at room temperature is described. A wide range of arenesulfonyl and alkanesulfonyl azides was obtained in excellent yields under mild conditions. [GRAHPICS].

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