Journal
JOURNAL OF SULFUR CHEMISTRY
Volume 33, Issue 4, Pages 413-418Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/17415993.2012.693491
Keywords
deoxygenation; sulfoxides; sulfides; iodine; thioacetic acid
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Funding
- Azad Islamic University of Qeshm
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An effective procedure for deoxygenation of sulfoxides to sulfides using thioacetic acid as a reducing agent and a catalytic amount of I-2 in MeCN at ambient temperature has been developed. Using this protocol, a variety of sulfoxides including benzyl, allyl, alkyl and aryl sulfoxides have been successfully reduced to the corresponding sulfides in excellent yields. [GRAPHICS] .
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