Journal
JOURNAL OF SULFUR CHEMISTRY
Volume 32, Issue 4, Pages 335-343Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/17415993.2011.593634
Keywords
catalytic oxidation; iron-Schiff base; sulfide; urea-hydrogen peroxide; nitrogen donor ligands
Categories
Funding
- Research Council of Sharif University of Technology
Ask authors/readers for more resources
The oxidation of sulfides to sulfoxides with hydrogen peroxide in good yield and high selectivity has been catalyzed very effectively by a series of Schiff base salen-type iron complexes in a monophasic medium (CH2Cl2/CH3OH) at ambient temperature. The results of the present study show that the reaction rate strongly depends on both catalyst steric effects and steric and electronic properties of sulfides. In the system, the electronic spectral studies are applied to explain the formation of a reactive (salen) Fe=O intermediate. [GRAPHICS] .
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available