4.1 Review

Reduction of oxygenated organosulfur compounds

Journal

JOURNAL OF SULFUR CHEMISTRY
Volume 29, Issue 1, Pages 53-97

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/17415990701684776

Keywords

reduction; deoxygenation; reductive coupling; sulfoxides; sulfides; thioethers; sulfonyl halides; sulfonyl derivatives; sulfenyl halides; sulfinyl halides; sulfonic acids; thiosulfonates; disulfides, oxidative coupling

Funding

  1. Shiraz University Research Council
  2. TWAS Chapter of Iran at ISMO
  3. Medicinal & Natural Products Chemistry Research Centre of Shiraz University of Medical Sciences

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A comprehensive review on deoxygenation of sulfoxides to thioethers and reductive coupling of sulfonyl, sulfinyl and sulfenyl halides, sulfinates and thiosulfonates to their corresponding disulfides are discussed with different reagents and catalysts. The reported mechanisms for these transformations are also addressed.

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