Journal
JOURNAL OF SOLUTION CHEMISTRY
Volume 43, Issue 2, Pages 404-420Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10953-014-0128-9
Keywords
Surface tension; [C(n)mim][NTf2]; Alcohols
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Funding
- Ministry of Economy and Competitiveness of Spain [CTQ2012-33359]
- European Regional Development Fund (ERDF)
- Directorate General for R+D+i of the Xunta de Galicia through Galician Network on Ionic Liquids, REGALIs [CN 2012/120]
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New experimental surface tension data have been provided at 283.15, 298.15, 313.15 K and atmospheric pressure for binary mixtures of 1-butyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)imide and 1-octyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl) imide ionic liquids with the alcohols: methanol, ethanol, 1-propanol, 2-propanol, l-butanol and 1-pentanol. The experimental results show that the surface tensions of these mixtures depend systematically on the alkyl chain length of the ionic liquid and alcohol, composition and temperature. Surface tension changes on mixing have been calculated and adequately fitted by the Redlich-Kister polynomial equation. The adjustable parameters and the standard deviations between experimental and calculated values are reported.
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