Journal
JOURNAL OF SOLUTION CHEMISTRY
Volume 40, Issue 7, Pages 1234-1257Publisher
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10953-011-9718-y
Keywords
Electrical conductances of symmetrical and unsymmetric electrolytes; Molar and equivalent limiting conductances; Ion association constants; Methanol; Ethanol; 1-Propanol; Dimethyl sulfoxide; Acetonitrile; Formamide; N-methylformamide; N,N-dimethylformamide; N-methylacetamide; N,N-dimethylacetamide
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Conductivities of symmetrical and unsymmetrical electrolytes of 2:2, 3:3, 2:1, 3:1 and 1:3 charge types in pure organic solvents (methanol, ethanol, 1-propanol, dimethyl sulfoxide, acetonitrile, formamide, N-methylformamide, N,N-dimethylformamide, N-methylacetamide and N,N-dimethylacetamide) were analyzed using the Quint-Viallard conductivity equation and taking into account the ion association effect. The molar limiting conductances and the ion association constants were determined for various multivalent electrolytes in these solvents using the literature conductivities. In many cases, for the first time, it was possible to obtain consistent values of the limiting ionic conductances in organic solvents.
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