Journal
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
Volume 19, Issue 1, Pages 281-288Publisher
SPRINGER
DOI: 10.1007/s10008-014-2556-2
Keywords
Lithium manganese phosphate; Two-step solid-state synthesis; Electrochemical performance; Lithium-ion battery
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Funding
- Natural Science Foundation of China [50902038]
- National High Technology Research and Development Program (863 Program) of China [2012AA110203]
- Heilong Jiang Postdoctoral Funds for Scientific Research Initiation [LBH-Q12084]
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LiMnPO4/C powders have been prepared by a solid-state method with sucrose as carbon source. The structure, morphology, and electrochemical performance of the LiMnPO4/C samples have been characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (SEM), transmission electronic microscopy (TEM), galvanostatic charge and discharge, electrochemical impedance spectroscopy (EIS), and cyclic voltammetry (CV). The LiMnPO4/C sample prepared by the two-step solid-state method exhibits a specific capacity of 156 mA h g(-1) after 40 cycles, and over 90 % of the initial capacity can be retained with a charge-discharge rate of 0.5 C and a voltage range of 2.5-4.4 V at 50 A degrees C. The improvement of electrochemical performance attributes to the highly uniform distribution of the minimizing particle size as well as the superior electrical conductivity of the carbon-coated nano-LiMnPO4 materials by facile two-step solid-state synthesis.
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