Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 200, Issue -, Pages 179-188Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2013.01.045
Keywords
Zeolite; Hollow structure; Hydrothermal synthesis; Organosilane; Dissolution-recrystallization
Funding
- 973 Program of China [2010CB732300]
- National Natural Science Foundation of China [20973058, 21273071]
- Science and Technology Commission of Shanghai Municipality [10dz2220500]
- Fundamental Research Funds for the Central Universities, China
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Hollow zeolite microspheres have been hydrothermally synthesized in the presence of organosilanes via a dissolution-recrystallization procedure. In the presence of organosilanes, zeolite particles with a core/shell structure formed at the first stage of hydrothermal treatment, then the core was consumed and recrystallized into zeolite framework to form the hollow structure during the second hydrothermal process. The influence of organosilanes was discussed, and a related dissolution-recrystallization mechanism was proposed. In addition, the hollow zeolite microspheres exhibited an obvious advantage in catalytic reactions compared to conventional ZSM-5 catalysts, such as in the alkylation of toluene with benzyl chloride. Crown Copyright (c) 2013 Published by Elsevier Inc. All rights reserved.
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