Core-shell TiO2 microsphere with enhanced photocatalytic activity and improved lithium storage

Inorganic hollow core-shell spheres have attracted considerable interest due to their singular properties and wide range of potential applications. Herein a novel facile generic strategy of combining template assisted and solvothermal alcoholysis is employed to prepare core-void-shell anatase TiO2 nanoparticle aggregates with an excellent photocatalytic activity, and enhanced lithium storage in large quantities. Amorphous carbon can be loaded on the TiO2 nanoparticles uniformly under a suitably formulated ethanol/water system in the solvothermal alcoholysis process, and the subsequent calcination results of the formation of core-shell-shell anatase TiO2 nanoparticle aggregates. The intrinsic core-void-shell nature as well as high porosity of the unique nanostructures contributes greatly to the superior photocatalytic activity and improved performance as anode materials for lithium ion batteries. (C) 2013 Elsevier Inc. All rights reserved.