Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 192, Issue -, Pages 34-37Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2012.03.037
Keywords
Cesium nickel chloride; Cesium nickel bromide; Cesium nickel iodide; Hydrothermal synthesis; X-ray crystal structure
Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [De-AC36-08G028308]
- U.S. Department of Energy, Basic Energy Sciences, Chemical Sciences, Biosciences, and Geosciences Division and Division of Materials Science and Engineering [ERB15522]
- NSF-NSEC
- NSF-MRSEC
- Keck Foundation
- State of Illinois
- Northwestern University
- International Institute of Nanotechnology (IIN)
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During reinvestigation of the hydrothermal synthesis reported earlier of the compound cesium nickel phosphide, CsNiP, we arrived at a new route to the synthesis of the cesium nickel halide compounds CsNiX3 (X=Cl, Br, I). The method has also been shown to extend to cobalt and iron compounds. Single crystals of these compounds were synthesized in phosphoric acid in sealed autoclaves. Their structures were determined by single-crystal X-ray diffraction methods. The compounds crystallize in the hexagonal space group P6(3)/mmc in the BaNiO3 structure type. The synthetic method and the resultant crystallographic details for CsNiCl3 are essentially identical with those reported earlier for the synthesis and structure of CsNiP. (C) 2012 Elsevier Inc. All rights reserved.
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