Ti2GaC, Ti4GaC3 and Cr2GaC-Synthesis, crystal growth and structure analysis of Ga-containing MAX-phases Mn+1GaCn with M = Ti, Cr and n=1, 3

Single crystals of Ga-containing MAX-phases Ti2GaC, Ti4GaC3, and Cr2GaC were grown from a metallic melt generated by an excess of Ga. This technique allows the crystal growth at different temperatures to control the product distribution. Compounds developed were Ti2GaC and TiC at 1500 degrees C, and Ti2GaC and Ti4GaC3 at 1300 degrees C. Crystal structures were refined from single crystal data. Ti2GaC and Cr2GaC were previously known, and belong to the Cr2AlC type as well as the solid solutions V2Ga1-xAlxC and Cr2Ga1-xAlxC. Ti4GaC3 is one of the few 413-phases (P6(3)/mmc, a = 3.0690(4)angstrom, c = 23.440(5)angstrom) and the first Ga-containing representative. The crystal structures of MAX-phases are intergrowths of layers of an intermetallic MGa in a hexagonal stacking sequence with carbidic layers (MC)(n) of the NaCl type. The thickness of the layer depends from the value of n. The results of the structure refinements also demonstrate that also the structural details follow this description. (C) 2009 Elsevier Inc. All rights reserved.