Journal
JOURNAL OF SOLID STATE CHEMISTRY
Volume 181, Issue 5, Pages 1204-1212Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jssc.2008.02.034
Keywords
modified ceria; solid solution; optical properties; UV absorbers
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Several approaches have been investigated to prepare fluorite-type compositions within the (1-x) CeO2-xYO(1.5) system. The optical properties of the resulting modified-ceria materials have been characterized in order to evaluate their potential abilities as inorganic UV absorbers. Diffuse reflectance analyses reveal a strong optical absorption between 390 and 400 nm for all substituted compositions and the spectral selectivities are estimated suitable for the targeted application. Additionally, time resolved microwave conductivity (TRMC) and phenol photodegradation analyses do not indicate any photocalatytic activity for these compositions. Aqueous colloidal suspensions of the Ce(0.7)y(0.3)O(1.85) UV absorber have been carried out. (C) 2008 Elsevier Inc. All rights reserved.
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