Journal
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
Volume 70, Issue 2, Pages 245-253Publisher
SPRINGER
DOI: 10.1007/s10971-013-3155-x
Keywords
Sol-gel; Click chemistry; CuAAC; Organosilanes; Nanoparticles
Categories
Funding
- CNRS
- Agence Nationale pour la Recherche [ANR P2N 2010 MECHANANO, ANR P2N 2012 NanoptPDT]
- Direction Generale de l'Armement (PhD Grant)
- Czech Science Foundation [P108/12/1356]
- BAR-RANDE project [MSMT 7AMB12FR004]
- French embassy in Prague
- Limousin region through Theranostic program
- Partner University Fund, a program of FACE
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The combination of the copper-catalyzed alkyne-azide cycloaddition (CuAAC) reaction with sol-gel processing enables the versatile preparation of sol-gel materials under different shapes with targeted functionalities through a diversity-oriented approach. In this account, the development of the CuAAC reaction under anhydrous conditions for the synthesis of sol-gel precursors and for the assembling of magnetic nanoparticles on self-assembled monolayers is related, as well as the use of the classical CuAAC methodologies for the functionalization of mesoporous silica nanoparticles and microdots arrays. Coupling CuAAC and Sol-Gel will result in simplified preparations of multifunctional materials with controlled morphologies.
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