Journal
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY
Volume 58, Issue 1, Pages 114-120Publisher
SPRINGER
DOI: 10.1007/s10971-010-2363-x
Keywords
Sol-gel hybrid material; Methacrylate zirconium sioxane; Degree of condensation; Optical transparency; High refractive index
Categories
Funding
- Ministry of Knowledge Economy (MKE, Korea) [10006932]
- Korea Institute of Industrial Technology(KITECH) [10006932] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Ask authors/readers for more resources
Methacrylate zirconium siloxane (MZS) resin was synthesized by a sol-gel reaction of 3-(trimethoxysilyl)propyl methacrylate, diphenylsilanediol, and zirconium n-propoxide chelated with methacrylic acid. Also, propylene glycol monomethyl ether acetate was added as a solvent to synthesize a homogeneous and long-term stable resin by controlling the reactivity among the precursors. A High condensation degree of the resin and the formation of Si-O-Zr hetero-metal bonds were verified by Si-29 NMR and FT-IR spectroscopy. The MZS resin was spin-coated and photo-polymerized to fabricate a highly transparent MZS hybrimer coating film. The refractive index and dielectric constant of the film increased according to the zirconium content, up to 1.59 and 3.65, respectively.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
