Journal
JOURNAL OF SEPARATION SCIENCE
Volume 36, Issue 9-10, Pages 1530-1536Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jssc.201201059
Keywords
Aqueous biphase system; Ionic liquids; Micellar liquid chromatography
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This paper is devoted to application of ionic liquids as surfactants in LC of organic compounds, derivatives of 1,4-thiosemicarbazides. According to HPLC requirements the most advantageous conditions such as transparency for ultraviolet light, low CMC, additional inorganic salt additives, and appropriate organic solvent were established. The CMC was determined using conductivity measurements. Suitability of two different stationary phases: RP-C18 and cyanopropyl bonded phase was examined under micellar conditions. Chosen ionic liquid surfactant was compared to common traditional amphiphilic reagent - SDS. Elaborated on chromatographic micellar conditions were tested as a pilot technique for prediction of distribution coefficients of organic analytes in ionic liquid-based aqueous two-phase system.
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