Journal
PHYTOCHEMISTRY
Volume 117, Issue -, Pages 144-153Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.phytochem.2015.06.009
Keywords
Baeyer-Villiger monooxygenase; Screening; Fungi; Phylum; Ascomycetes; Basidiomycetes; Zygomycetes; Regioselectivity; Enantioselectivity
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Funding
- Centre National de la Recherche Scientifique - France (CNRS)
- Ministry of Foreign Affairs - France (MAE)
- Ministry of Higher Education and Scientific Research - France (MESR)
- Ministry of Education, Science, Culture and Sport - Slovenia
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Out of 107 fungal strains belonging to three phyla (Ascomycota, Basidiomycota and Zygomycota) and 46 genera, 86 exhibited Baeyer-Villiger monooxygenase (BVMO) activity against racemic bicyclo[3.2.0]heptenone. The strains were classified into three profiles based on regio- and enantioselectivity. Statistical analyses of our results, extended by literature data, showed that these profiles could be related to the taxonomic classification of the strains, and suggest that the BVMOs from the Zygomycota phylum may be different in their primary structures from established ones. (C) 2015 Elsevier Ltd. All rights reserved.
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