Upconversion properties of Y2O3:Er films prepared by sol-gel method

Y2O3:Er3+ films were prepared by a simple sol-gel process. The structural properties Of Y2O3:Er3+ films were characterized with X-ray diffraction, Fourier transform infrared spectroscopy and field emission scanning electron microscopy. The results indicated that the Y2O3:Er3+ films might have high upconversion efficiency because of their low vibrational energy. Under 785 and 980 nm laser excitation, the samples showed green (H-2(1/2)-->I-4(15/2), S-4(3/2)-->I-4(15/2)) and red (F-2(9/2)-->I-4(15/2)) upconversion emissions. The upconversion mechanisms were studied in detail through laser power dependence. Excited state absorption and energy transfer process were discussed as possible upconversion mechanisms. The cross relaxation process in Er3+ was also investigated.