Journal
JOURNAL OF RAMAN SPECTROSCOPY
Volume 42, Issue 4, Pages 799-802Publisher
WILEY-BLACKWELL
DOI: 10.1002/jrs.2759
Keywords
sodium molybdate; sodium tungstate; phase transition; Raman scattering
Categories
Funding
- CNPq [480364/2008-7]
Ask authors/readers for more resources
Temperature-dependent Raman studies on Na2WO4 and Na2MoO4 crystals were performed in order to obtain information on structural changes induced by temperature evolution. The stability of the cubic phase of Na2WO4 and Na2MoO4 crystals was assessed and our results indicate that this phase is stable in the 8-823 K and 15-773 K ranges for Na2WO4 and Na2MoO4, respectively. The crystal of Na2WO4 shows a phase transition occurring at 833 K. Na2MoO4 undergoes a sequence of three phase transitions, which were observed at 783-803, 823-913 and 943-950 K. In both crystals, a strong first-order phase transition occurs as indicated by the behavior of the Raman modes: the Raman bands split and new bands appear below 100 cm(-1). These transitions are connected with tilting and/or rotations of the WO(4)and MoO4 tetrahedra, which leads to a disorder at the WO(4)and MoO4 sites. Copyright (C) 2010 John Wiley & Sons, Ltd.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available