Journal
JOURNAL OF RAMAN SPECTROSCOPY
Volume 42, Issue 7, Pages 1562-1566Publisher
WILEY
DOI: 10.1002/jrs.2881
Keywords
Raman spectroscopy; high pressure; hydrotalcites; dicarboxylates; structure
Categories
Funding
- Natural Sciences and Engineering Research Council of Canada [228253]
- Australian Research Council
- Queensland University of Technology
Ask authors/readers for more resources
The results of pressure-tuning Raman spectroscopic, X-ray powder diffraction and solid-state C-13-NMR studies of selected dicarboxylate anions intercalated in a Mg-Al layered double hydroxide lattice are reported. The pressure dependences of the vibrational modes are linear for pressures up to 4.6 GPa, indicating that no phase transitions occur. The interlayer spacings show that the oxalate, malonate and succinate dianions are oriented perpendicular to the layers, but the glutarate and adipate are tilted. The solid-state C-13-NMR spectra of these materials show full chemical shift anisotropy and, therefore, the anions are not mobile at room temperature. Copyright (c) 2011 John Wiley & Sons, Ltd.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available