4.5 Article

Selective extraction of 90Sr in urine using 4′4(5)di-tert-butyl dicyclohexano-18-crown-6 ether immobilized on polyacrylamide-coated magnetic nanoparticles

Journal

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volume 303, Issue 1, Pages 1053-1057

Publisher

SPRINGER
DOI: 10.1007/s10967-014-3605-0

Keywords

Sr-90; Human urine; Bioassay; Magnetic nanoparticles; Polyacrylamide coating; Liquid scintillation counting

Funding

  1. Natural Sciences and Engineering Research Council (NSERC) Canada
  2. [CRTI06-230RD]

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4'4 ''(5 '')di-tert-butyl dicyclohexano-18-crown-6 ether was immobilized onto the surface of iron oxide magnetic nanoparticles coated with divinylbenzene-crosslinked polyacrylamide. The coated magnetic nanoparticles were successful in selectively extracting Sr-90 from human urine samples, as confirmed by the liquid scintillation counting spectra. This method offers excellent repeatability for Sr-90 in urine bioassay, with a relative precision of 8 % when five urine samples collected from different donors were spiked with1.58 Bq of Sr-90 and analyzed.

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