4.5 Article

Solvent extraction of uranium(VI) and separation of vanadium(V) from sulfate solutions using Alamine 336

Journal

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY
Volume 285, Issue 2, Pages 301-308

Publisher

SPRINGER
DOI: 10.1007/s10967-010-0552-2

Keywords

Uranium(VI); Solvent extraction; Vanadium(V) separation; Sulfate solutions; Alamine 336

Funding

  1. Ministry of Knowledge Economy of Korea (MKE)

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The present scientific study on uranium(VI) solvent extraction and vanadium(V) separation from sulfate solutions using Alamine 336 as an extractant diluted in kerosene was established. The preliminary experiments indicating the uranium extraction process will follow the solvation as well as ion-exchange mechanisms. In the present acid region (0.1-1.0 mol dm(-3) H2SO4) it showing the ion-exchange type mechanism. Time (1-120 min) and temperature (25-55 A degrees C) not influencing the present extraction system. Other experimental parameters like loading capacity of Alamine 336, stripping of uranium from loaded organic phase, recycling of Alamine 336 and separation of uranium(VI)/vanadium(V) was studied.

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