Journal
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER
Volume 113, Issue 11, Pages 1170-1194Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jqsrt.2012.02.013
Keywords
Cyanogen iodide ICN; Infrared spectra; Rotational spectra; Global rovibrational analysis; Coriolis resonance
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Funding
- Fond de la Recherche Scientifique de Belgique (FRS-FNRS)
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The infrared absorption spectrum of ICN has been recorded in the region 200-5000 cm(-1) with a Bruker 120HR interferometer, and several tenthousands of lines have been measured with a precision between 0.0001 and 0.001 cm(-1). Most of these lines have been assigned. These new data were combined with transitions previously measured in the microwave and millimeterwave ranges. After a band-by-band analysis including 292 subbands a rovibrational global analysis has been performed using all available data. The main resonances are the rotational C-type resonance and the strong Fermi resonance coupling the states nu(1)=1 and nu(2)=2 via the cubic anharmonic constant k(122). In addition, many local resonances became evident by the observation of the corresponding avoided crossings. In particular, there is a direct coupling between the states (400) and (240) due to the fourth-order resonance k(112222). There is also a fourth-order Coriolis resonance governed by C-11222 responsible for interactions between the (200) and (030) states. All these interactions have been taken into account in one-step diagonalization procedures. A statistical agreement with the 6344 selected pieces of data has been obtained, with an estimated standard deviation (sigma) over cap =0.660. All those data and their deviations are given in the first depository. A set of 109 parameters including 24 off-diagonal anharmonic and Coriolis resonance parameters has been derived. They have been used to calculate effective rovibrational parameters for all substates up to more than 6000 cm(-1), also listed in the second depository. (C) 2012 Elsevier Ltd. All rights reserved.
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