Journal
JOURNAL OF POWER SOURCES
Volume 399, Issue -, Pages 238-245Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2018.07.104
Keywords
Electron transport; Interfacial interaction; Cobalt hydroxide; Supercapacitor
Funding
- National Key R&D Program of China [2016YFA0200400]
- Jilin Province/Jilin University co-Construction Project-Funds for New Materials [SXGJSF2017-3, Branch 2/440050316A36]
- Program for JLU Science and Technology Innovative Research Team (JLUSTIRT)
- Double-First Class Discipline for Materials Science Engineering
- Special Funding for Academic Leaders at Jilin University
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The interaction between active materials and conductive additives is complicated but crucial within electro-chemical energy storage devices. Here, we first identify that CH2 groups drive the compositing process, leading to an effective formation of Co-O-C chemical bonding serving as the bridge between reduced graphene oxide (rGO) and hydroxide. Due to the enhanced electron transport, a dramatically improved specific capacity is achieved as high as 1368 F/g for rGO/Co(OH)(2) electrode at a current density of 0.5 A/g. Thus, we provide new insights into graphene/hydroxide compositing mechanism, which has a significant impact on enhancing electron transport for a variety of graphene/hydroxide in energy storage systems.
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