4.8 Article

Cobalt iron carbonate hydroxide hydrate on 3D porous carbon as active and stable bifunctional oxygen electrode for Zn-air battery

Journal

JOURNAL OF POWER SOURCES
Volume 402, Issue -, Pages 388-393

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2018.09.064

Keywords

Cobalt iron carbonate hydroxide; Porous carbon; Zn-air battery; Oxygen evolution reaction; Oxygen reduction reaction

Funding

  1. National Natural Science Foundation of China [21476096]
  2. Innovation projects of Guangdong universities [2015KTSCX014]
  3. Natural Science Foundation of Guangdong Province, China [2017A030313048]

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We report cobalt iron carbonate hydroxide hydrate on three-dimensions porous carbon as active and stable bifunctional oxygen electrode for Zn-air battery. The difference between oxygen evolution reaction potential at 10 mA cm(-2) and oxygen reduction reaction half-wave potential is only 0.804 V, outperforming most catalysts reported to date. The cobalt iron carbonate hydroxide hydrate on porous carbon serves as a superb air cathode electrocatalyst in high-performance rechargeable Zn-air battery.

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