Journal
JOURNAL OF POWER SOURCES
Volume 268, Issue -, Pages 469-475Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2014.06.054
Keywords
Copper nanoparticle; Alkyne; Photoluminescence; Cuprous oxide; Rotating ring-disk electrode; Oxygen reduction
Funding
- National Science Foundation [CHE - 1012258, CHE - 1265635]
- Direct For Mathematical & Physical Scien [1265635] Funding Source: National Science Foundation
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1012258] Funding Source: National Science Foundation
- Division Of Chemistry [1265635] Funding Source: National Science Foundation
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Stable alkyne-capped copper nanoparticles were prepared by chemical reduction of copper acetate with sodium borohydride in the presence of alkyne ligands. Transmission electron microscopic measurements showed that nanoparticles were well dispersed with a diameter in the range of 4-6 nm. FOR and photoluminescence spectroscopic measurements confirmed the successful attachment of the alkyne ligands onto the nanoparticle surface most likely forming Cu-C interfacial bonds. XPS measurements indicated the formation of a small amount of CuO in the nanoparticles with a satellite peak where the binding energy red-shifted with increasing Cu(II) concentration. Cu2O was also detected in the nanoparticles. Similar results were observed with commercial CuO nanoparticles. Electrochemical studies showed that the as-prepared alkyne-capped copper nanoparticles exhibited apparent electrocatalytic activity in oxygen reduction in alkaline media, a performance that was markedly better than those reported earlier with poly- or single-crystalline copper electrodes; and the fraction of peroxides in the final products decreased with decreasing concentration of oxide components in the nanoparticles. (C) 2014 Elsevier B.V. All rights reserved.
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