Journal
JOURNAL OF POWER SOURCES
Volume 256, Issue -, Pages 153-159Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2014.01.038
Keywords
Cobalt ferrite; Flower-like microspheres; Anode; Lithium ion battery
Funding
- Program for Innovative Research Team in University of Ministry of Education of China [IRT13037]
- Key Science and Technology Innovation Team of Zhejiang Province [2010R50013]
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CoFe2O4 flower-like microspheres are prepared via a surfactant- and template-free method, involving the controlled hytrothermal synthesis firstly and a subsequent thermal decomposition treatment. The microspheres with diameters of 3-4 mu m are characterized by the assembly of numerous porous and interconnected lamella structures. Lithium-ion batteries electrodes based on the as-prepared CoFe2O4 microspheres show a high specific capacity of 733.5 mAh g(-1) after 50 cycles at a current density of 200 mA g(-1) and a good cyclic stability, as well as excellent rate capability. The enhanced electrochemical performance can be attributed to the hierarchical microsphere structure with high sufficient interfacial contact area between the microspheres and electrolyte, the short diffusion distance of Li+, better accommodation of structural stress and volume change with the lithiation/delithiation process. It is suggested that the CoFe2O4 microsphere is one of the most promising candidates for high-performance lithium-ion batteries. (C) 2014 Elsevier B.V. All rights reserved.
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