Journal
JOURNAL OF POWER SOURCES
Volume 246, Issue -, Pages 449-456Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2013.07.115
Keywords
Porous; Manganese dioxide; Diatomite; Electrochemical properties
Funding
- National Natural Science Foundation of China [51104194]
- Ministry of Education of China [20110191120014]
- 43 Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
- Fundamental Research Funds for the Central Universities [CDJZR12248801, CDJZR12135501]
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The hierarchical and porous MnO2-modified diatomite structures are prepared for the first time by a one-pot hydrothermal method. The morphology and structure of MnO2-modified diatomite hierarchical structures are examined by focus ion beam scanning electron microscopy (FIB/SEM) and X-ray diffraction spectroscopy (XRD). The results show that Birnessite-type MnO2 nanosheets are observed to grow vertically on the purified diatomite, thus building hierarchical architecture. Furthermore, the electrochemical properties of the MnO2-modified diatomite electrodes are elucidated by cyclic voltammograms, galvanostatic charge/discharge tests and electrochemical impedance spectroscopy in 1 M Na2SO4 electrolyte. The electrochemical results demonstrate that the MnO2-modified diatomite electrode exhibits highly reversible features and good rate abilities, respectively. Significantly, it exhibits the specific capacitance of 202.6 F g(-1) for the MnO2-modified diatomite and 297.8 F g(-1) for the MnO2 nanostructures after etching the diatomite. The capacitance retention of 95.92% over 5000 cycles further indicates the suitability of the low-cost MnO2-modified diatomite structure as a potential electrode material for supercapacitors. (C) 2013 Elsevier B.V. All rights reserved.
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