Journal
JOURNAL OF POWER SOURCES
Volume 246, Issue -, Pages 253-259Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2013.07.076
Keywords
Lithium-sulfur batteries; Sulfur electrode; Carbon materials; Electrode protection; Nation film
Funding
- National Basic Research Program of China [2009CB220105]
- International Cooperation Program with German [2012DFG61480]
- International Cooperation Program with France [2011DFA70570-4]
- National High Technology Research and Development Program of China [2013AA050901]
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In this paper, a nafion coated electrode is prepared to improve the performance of lithium sulfur batteries. It is demonstrated from a series of measurements that the nafion layer is quite effective in reducing shuttle effect and enhancing the stability and the reversibility of the electrode. When measured under the rate of 0.2 C, the initial discharge capacity of the nafion coated electrode can reach 1084 mAh g(-1), with a Columbic efficiency of about 100%. After 100 charge/discharge cycles, this electrode can also deliver a reversible capacity of as high as 879 mAh g(-1). Significantly, the charge-transfer resistance of the electrode tends to be reducing after coated with an appropriate thickness of nafion film. The cation conductivity as well as anion inconductivity is considered to be the dominant factor for the superior electrochemical properties. (C) 2013 Elsevier B.V. All rights reserved.
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