Journal
JOURNAL OF POWER SOURCES
Volume 263, Issue -, Pages 118-124Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2014.03.140
Keywords
Thermoplastic polyurethane; Poly(vinylidene fluoride-co-hexafluoropropylene); Gel polymer electrolyte; Electrospinning
Funding
- Youth Project of National Nature Science Foundation of China [51103124, 51203131]
- Hunan Province Universities Innovation Platform of Open Fund Project [11K067]
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A novel electrospun gel polymer electrolyte (GPE) consisting of thermoplastic polyurethane (TPU) and poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) is prepared and investigated. Its characteristics are investigated by scanning electron microscopy (SEM), thermal analysis (TGA). The GPE shows a maximum ionic conductivity of 4.1 x 10(-3) S cm(-1) with electrochemical stability up to 5.5 V versus Li+/ Li at room temperature. In addition, it shows a first charge-discharge capacity of 168.8 mAh g(-1) when the gel polymer electrolyte (GPE) is evaluated in a Li/PE/LiFePO4 cell under 0.1 C-rate at the first cycle. What's more, there is microscale attenuation (1%) in the 30 cycles of charge and discharge tests. The TPU/PVDF-HFP membrane has a high tensile strength (8.4 +/- 03 MPa) and elongation at break (118.7 +/- 0.2)%. With the outstanding electrochemical and mechanical performance, it is very suitable for application in polymer lithium ion batteries. (C) 2014 Elsevier B.V. All rights reserved.
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