Journal
JOURNAL OF POWER SOURCES
Volume 224, Issue -, Pages 93-98Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2012.09.029
Keywords
Polymer electrolyte; Electrospinning; N-butyl-N-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)-imide; Poly(vinylidene difluoride-co-hexafluoropropylene); Lithium batteries
Funding
- STINT
- KRF in a joint Korea-Sweden program
- FORMAS
- Chalmers Area of Advance - Energy
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Poly(vinylidene difluoride-co-hexafluoropropylene) (PVdF-HFP) membrane was prepared by electrospinning. The membranes served as host matrices for the preparation of ionic liquid-based polymer electrolytes (ILPEs) by activation with non-volatile, highly thermally stable, and safe room temperature ionic liquid (RTIL) electrolytes; N-butyl-N-methyl-pyrrolidinium bis(trifluoromethanesulfonyl)imide (Py14TFSI) complexed with 1 M lithium bis(trifluoromethanesulfonyl)imide (LiTFSI). In this work, the first combination of electrospun PVdF-HFP fiber polymer host and pyrrolidinium-based ionic electrolyte was employed for highly stable lithium batteries. The ILPE exhibited low Li+-TFSI coordination, low crystallinity, high thermal stability, high electrochemical stability, and high ionic conductivity with a maximum of 1.1 x 10(-4) S cm(-1) at 0 degrees C. The ILPE exhibited good compatibility with a LiFePO4 electrode on storage and good charge-discharge performance in Li/ILPE/LiFePO4 cells at room temperature, delivering specific capacities of 143 and 115 mA h g(-1) at 0.1 and 1 C-rates. The ILPE also exhibited stable cycle properties and have therefore been demonstrated to be suitable for lithium battery applications. (C) 2012 Elsevier B.V. All rights reserved.
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