Journal
JOURNAL OF POWER SOURCES
Volume 233, Issue -, Pages 209-215Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2013.01.102
Keywords
Lithium ion battery; Cathode; Conductivity
Funding
- National Basic Research Program of China [2012CB932301]
- NSFC [51102146, 50825201]
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Super-aligned carbon nanotube (SACNT) films drawn from SACNT arrays are uniformly introduced into LiCoO2-Super P composite cathodes by a cold-rolling method, and a hybrid conductive network consisting of SACNTs and carbon black powders is obtained. This attempt results in reduced percolation threshold and increased conductivity of the LiCoO2-Super P cathodes with addition of less than 0.01 wt% of SACNTs. The strength and flexibility of the LiCoO2-Super P-SACNT composites can be improved significantly due to the excellent mechanical properties of SACNTs. The continuous SACNT films play an important role for the formation of a homogeneous network for long-range conductive pathways. Super P is also an essential component to form short-range conductive pathways. By comparing with control samples that only contain Super P or SACNT films, we demonstrate that the LiCoO2-Super P-SACNT composites possess the best cycling stability (150 mA h g(-1) at 0.1 C with a capacity retention of 99.7% after 50 cycles) and rate capability (87 mA h g(-1) at 5 C). Combining both short-range and long-range conduction, the hybrid Super P-SACNT conductive network manifests itself as a promising strategy to improve the battery performances with a minimum amount of conductive fillers. (C) 2013 Elsevier B.V. All rights reserved.
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