Journal
JOURNAL OF POWER SOURCES
Volume 232, Issue -, Pages 240-245Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2012.12.114
Keywords
Lithium batteries; Polyaniline; Layered material; Cobalt free cathode; High rate
Funding
- IT R&D program of MKE/KEIT [KI002176]
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We first report the ultra-fast charge discharge capability of organic inorganic (Li(Mn1/3Ni1/3Fe1/3)O-2-Polyaniline (PANI)) nanocomposites prepared by mixed hydroxide route and followed by polymerization of aniline monomers with different concentrations (0.1 and 0.2 mol concentration of PANI). Li-insertion properties are evaluated in half-cell configuration, test cell (Li/Li(Mn1/3Ni1/3Fe1/3)O-2-PANI) comprising 0.2 mol. PANI delivered the reversible capacity of similar to 127, similar to 114 and similar to 110 mAh g(-1) at ultra-high current rate of 5, 30 and 40 C, respectively with exceptional cycleability between 2 and 4.5 V vs. Li. Such an exceptional performance is mainly due to the conducting pathways promoted by PANI network and it is revealed by impedance measurements. This result certainly provides the possibility of using such layered type Fe based cathode materials in high power Li-ion batteries to drive zero emission vehicles such as hybrid electric vehicles or electric vehicles applications in near future. Crown Copyright (C) 2013 Published by Elsevier B.V. All rights reserved.
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