Journal
JOURNAL OF POWER SOURCES
Volume 230, Issue -, Pages 298-302Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2012.12.085
Keywords
Silicon carbide nanowires; Micro-supercapacitor; Aqueous electrolyte; Electrochemical energy storage
Funding
- DARPA ST Center
- CIEMS
- Siemens CKI program
- National Science Foundation through the Center of Integrated Nanomechanical Systems [DMR-1207053, EEC-0832819]
- Direction Generale de l'Armement (DGA)
- National Science Foundation
- U.S. Department of Energy [DE-AC02-05CH11231]
- Nanotechnology and Functional Materials Center
- European FP7 [245916]
- Ministry of Education and Science of the Republic of Serbia [172054]
- Direct For Mathematical & Physical Scien [1207053] Funding Source: National Science Foundation
- Division Of Materials Research [1207053] Funding Source: National Science Foundation
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The effectiveness of silicon carbide (SiC) nanowires (NW) as electrode material for micro-supercapacitors has been investigated. SiC NWs are grown on a SiC thin film coated with a thin Ni catalyst layer via a chemical vapor deposition route at 950 degrees C. A specific capacitance in the range of similar to 240 mu F cm(-2) is demonstrated, which is comparable to the values recently reported for planar micro-supercapacitor electrodes. Charge-discharge studies demonstrate the SiC nanowires exhibit exceptional stability, with 95% capacitance retention after 2 x 10(5) charge/discharge cycles in an environmentally benign, aqueous electrolyte. (C) 2013 Elsevier B.V. All rights reserved.
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