Journal
JOURNAL OF POWER SOURCES
Volume 205, Issue -, Pages 483-486Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2012.01.070
Keywords
Electrochemical impedance spectroscopy; Lithium ion battery; Equivalent circuit; Diffusion impedance; SEI
Funding
- Research & Development Initiative for Scientific Innovation of New Generation Batteries from the New Energy and Industrial Technology Development Organization of Japan
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [20002006] Funding Source: KAKEN
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To analyze impedance response of an electrochemical system, it is important to model the system with an adequate equivalent circuit. In the present work, an equivalent circuit was designed for the analysis of lithium ion batteries with the contributions of a variety of diffusion parameters resulting from the various particle sizes for the cathode and the solid-electrolyte interphase formed on the anode particles, as well as electrochemical reactions and inductive components. Residual errors resulting from the data fitting was investigated for a variety of equivalent circuits used. The electrochemical impedance of the electrodes in commercial lithium ion batteries at various states of charge was analyzed to evaluate the proposed circuit. (C) 2012 Elsevier B.V. All rights reserved.
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