Journal
JOURNAL OF POWER SOURCES
Volume 218, Issue -, Pages 320-330Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2012.07.012
Keywords
Multi-walled carbon nanotubes; Trimanganese tetraoxide; Palladium nanoparticles; Electro-oxidation; Alkaline direct methanol fuel cells
Funding
- National Natural Science Foundation of China [21163002, 21165004]
- Guangxi Natural Science Foundation of China [2010GXNSFF013001, 0728043]
- project of Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Guangxi Normal University)
- Ministry of Education of China [CMEMR2011-14]
- Innovation Plan in Graduate Education of Guangxi Province [2011106020703M48]
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A facile preparation route for Pd electrocatalyst (Pd-Mn3O4/MWCNTs) composed of similar to 3.5 nm Pd nanoparticles homogeneously anchored on Mn3O4 modified multi-walled carbon nanotubes (Mn3O4/MWCNTs) is reported. The morphology, component and crystallinity of the catalyst were characterized by means of different techniques. The electrochemical behavior of the Pd-Mn3O4/MWCNT composites was examined by cyclic voltammetry toward methanol electro-oxidation in alkaline media. Pd nanoparticles binding on the surface of the Mn3O4/MWCNTs exhibited improved electrocatalytic activity and anti-COads species poisoned ability compared to Pd/MWCNTs and Pd/XC-72 (Pd/commercial Vulcan XC-72 carbon black). This improved performance of the as-prepared electrocatalyst is attributed to the synergistic effect of Mn3O4 nanoparticles and MWCNTs. (C) 2012 Elsevier B.V. All rights reserved.
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