Journal
JOURNAL OF POWER SOURCES
Volume 209, Issue -, Pages 141-146Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2012.02.070
Keywords
Cobalt hydroxide; Nickel hydroxide; Composite; Supercapacitor; Lithium hydroxide; Electrolyte
Funding
- Scientific Research Foundation for Advanced Scholars of Qingdao Agricultural University [631015]
- Outstanding Young Scientists Incentive Foundation of Shandong Province [B52010NJ007]
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The supercapacitive performances of Co(OH)(2)/Ni(OH)(2) composites in lithium hydroxide solution are investigated in detail. Cyclic voltammetries and galvanostatic charge/discharge measurements reveal that LiOH is the most suitable electrolyte for the composite electrodes among MOH (M = Li, Na and K). The redox behavior of the Co(OH)(2)/Ni(OH)(2) composites different to that of the pure components shows that weight ratio of Co(OH)(2)/Ni(OH)(2) exerts a great influence on the capacitive performances. After 1000 continuous charge/discharge cycles, the capacitance retention ratio for the composite electrode with the weight ratio of 2/3 is elevated from 41.6% to 88.2% compared with pure Ni(OH)(2) electrode, exhibiting improved long-life cyclability. (C) 2012 Elsevier B.V. All rights reserved.
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