Journal
JOURNAL OF POWER SOURCES
Volume 196, Issue 18, Pages 7700-7706Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2011.04.033
Keywords
Graphite; Ionic liquid; Bis(fluorosulfonyl)imide; Lithium-ion battery; Solid electrolyte interface
Funding
- Academy of Sciences [AV0Z40320502]
- Grant Agency of the Academy of Sciences of the Czech Republic [KJB200320801, KJB200320901]
- Ministry of Education, Youth and Sports, Czech Republic [LC523]
- Ministry of Education, Science and Sport of Slovenia
- Slovenian Research Agency
- CO-NOT centre of excellence
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Lithium bis(fluorosulfonyl)imide (LiFSI) in 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR14TFSI) was successfully tested as an electrolyte for graphite composite anodes at elevated temperature of 55 degrees C. The graphite anode showed a good cyclability during the galvanostatic testing at C/10 rate and 55 degrees C with the capacity close to theoretical. The formation of SEI in different electrolytes was the subject of study using impedance spectroscopy on symmetrical cells containing two lithium electrodes. The 0.7m LiFSI in PYR14TFSI exhibits a good ionic conductivity (5.9 mS cm(-1) at 55 degrees C) along with high electrochemical stability and high thermal stability. These properties allow their potential application in large-scale lithium ion batteries with improved safety. (C) 2011 Elsevier B.V. All rights reserved.
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