4.8 Article

Reduced graphene oxide/tin oxide composite as an enhanced anode material for lithium ion batteries prepared by homogenous coprecipitation

Journal

JOURNAL OF POWER SOURCES
Volume 196, Issue 15, Pages 6473-6477

Publisher

ELSEVIER
DOI: 10.1016/j.jpowsour.2011.04.015

Keywords

Reducul graphene oxide; Tin oxide; Homogeneous coprecipitation; Lithium ion battery; Anode

Funding

  1. University of Texas at Austin
  2. U.S. Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [DE-SC001951]
  3. National Science Foundation [DMR-0907324]
  4. China Scholarship Council
  5. SRF for ROCS, SEM

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Reduced graphene oxide/tin oxide composite is prepared by homogenous coprecipitation. Characterizations show that tin oxide particles are anchored uniformly on the surface of reduced graphene oxide platelets. As an anode material for Li ion batteries, it has 2140 mAh g(-1) and 1080 mAh g(-1) capacities for the first discharge and charge, respectively, which is more than the theoretical capacity of tin oxide, and has good capacity retention with a capacity of 649 mAh g(-1) after 30 cycles. The simple synthesis method can be readily adapted to prepare other composites containing reduced graphene oxide as a conducting additive that, in addition to supporting metal oxide nanoparticles, can also provide additional Li binding sites to, perhaps, further enhance capacity. (C) 2011 Elsevier B.V. All rights reserved.

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