Journal
JOURNAL OF POWER SOURCES
Volume 196, Issue 20, Pages 8625-8631Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2011.06.016
Keywords
Lithium-ion battery; Positive electrode material; Layered oxide; Aluminium substitution; X-ray diffraction; Power electrochemical performance; Thermal stability
Funding
- Region Aquitaine
- Saft
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Li-1.11(Ni0.40Mn0.39Co0.16Al0.05)(0.89)O-2 was synthesized through coprecipitation of a mixed hydroxide followed by calcination with LiOH center dot H2O during 10h at 500 degrees C and 950 degrees C. Electrochemical tests and their comparison with those obtained for an industrial Li(Ni1_y-zCoyAlz)O-2 material reveal that Li-1.11(Ni0.40Mn0.39Co0.16Al0.05)(0.89)O-2 shows good charge-discharge performance, even at high rate according to a protocol well established by car-makers for testing power abilities of batteries for electric and hybrid electric vehicles. In addition, this material shows a significant improvement in thermal stability in the highly deintercalated state (charged state of the battery) over the industrial material. Equivalent (or higher) energy and power densities with a significantly greater thermal stability make of Li-1.11(Ni0.40Mn0.39Co0.16Al0.05)(0.89)O-2 an interesting candidate as positive electrode material for large lithium-ion batteries. (C) 2011 Elsevier B.V. All rights reserved.
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