Journal
JOURNAL OF POWER SOURCES
Volume 196, Issue 18, Pages 7760-7762Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2011.05.002
Keywords
Li-ion solid electrolyte; Lithium zirconium phosphate; Li-ion battery
Funding
- Office of Vehicle Technologies of the US Department of Energy [DE-AC02-05CH11231, 6805919]
- National Science Foundation [0959037]
- Div Of Chem, Bioeng, Env, & Transp Sys
- Directorate For Engineering [0959037] Funding Source: National Science Foundation
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Substitution of 5% of Zr by Ca in LiZr2(PO4)(3) transforms the structure to that of rhombohedral NASICON to give a room-temperature bulk Li-ion conductivity sigma(Li) approximate to 1.2 x 10(-4) S cm(-1), which is comparable to that of Li1.3Ti1.7Al0.3(PO4)(3) now being used as a solid Li-ion separator in test cells of novel Li-ion batteries. (C) 2011 Elsevier B.V. All rights reserved.
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