4.8 Article

Electrochemical properties of Li1.4Al0.4Ti1.6(PO4)3 synthesized by a co-precipitation method

Journal

JOURNAL OF POWER SOURCES
Volume 196, Issue 16, Pages 6943-6946

Publisher

ELSEVIER
DOI: 10.1016/j.jpowsour.2010.11.140

Keywords

Lithium ion electrolyte; All-solid-state lithium battery; Co-precipitation; Conductivity

Funding

  1. Natural Science Foundation of China (NSFC) [50973127, 50672114]
  2. 973 Project of China [2007CB209700]
  3. Science and Technology Commission of Shanghai Municipality [08DZ2210900]

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Sub-micron Li1.4Al0.4Ti1.6(PO4)(3) (LATP) ceramic powder is synthesized by a co-precipitation method which can be applied for mass production. A pure Nasicon phase is confirmed by X-ray diffraction analysis and the primary particle size of the product is 200-500 nm. The sinterability of LATP is investigated and the relative density of 97% reached at a sintering temperature as low as 900 degrees C for 6 h. The bulk lithium ionic conductivity of the sintered pellet is 2.19 x 10(-3) S cm(-1), and a total conductivity of 1.83 x 10(-4) S cm(-1) is obtained. (C) 2010 Elsevier B.V. All rights reserved.

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