Effect of nano-silica filler in polymer electrolyte on Li dendrite formation in Li/poly(ethylene oxide)-Li(CF3SO2)2N/Li

Lithium dendrite growth in Li/poly(ethylene oxide) (PEO)-Li(CF3SO2)(2)N (LiTFSI)-nano-SiO2/Li was examined using direct in situ observation under galvanostatic conditions at 60 degrees C. Both the onset time of dendrite formation and the short-circuit time of the cells were extended by the addition of nano-SiO2 filler into the polymer electrolyte, of which an acid-modified nano-SiO2 filler was the most effective. The onset time was dependent on the current density in the range from 0.1 to 1.0 mA cm(-2). Li dendrite growth in Li/PEO18LiTFSI/Li at 60 degrees C for current densities of 0.1 and 0.5 mA cm(-2) started at 125 and 15 h, respectively. PEO18 LiTFSI with addition of 10 wt% acid-modified 50 nm SiO2 showed extended dendrite formation onset times of 250 h at 0.1 mA cm(-2) and 32h at 0.5 mA cm(-2). The suppression of dendrite formation at the Li/PEO18 LiTFSI interface could be explained by enhancement of the conductivity and suppression of the interface resistance between lithium and the polymer electrolyte by addition of the nano-SiO2 filler. The electrical conductivity of 4.1 x 10(-4) S cm(-1) and interface resistance of 405 Omega cm(2) for PEO18 LiTFSI at 60 degrees C were respectively increased to 7.2 x 10(-4) S cm(-1) and decreased to 77 Omega cm(2) by the addition of 10 wt% acid-modified nano-SiO2. (C) 2010 Elsevier B.V. All rights reserved.