4.8 Article

The conductivity of pyrrolidinium and sulfonylimide-based ionic liquids: A combined experimental and computational study

Journal

JOURNAL OF POWER SOURCES
Volume 195, Issue 7, Pages 2074-2076

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2009.10.029

Keywords

Ionic liquid; Lithium battery; C3mpyr; C4mpyr; Conductivity; Ab initio

Funding

  1. Swedish Energy Agency
  2. Swedish Research Council
  3. Stiftelsen Futura
  4. European Commission [TST4-CT-2005-518307]
  5. ILLIBATT [NMP3-CT-2006-033181]

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Ionic conductivity is a fundamental property of ionic liquids with its origin and exact nature under debate. Using a specially selected system of pyrrolidinium cations (PYR1x, x = 3,4) and sulfonylimide anions (FSI, TFSI, BETI, and IM14)-based ionic liquids we observe a simple and accurate connection between ab initio computed cation and anion volumes and measured molar ionic conductivities. (C) 2009 Elsevier B.V. All rights reserved.

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