Journal
JOURNAL OF POWER SOURCES
Volume 195, Issue 1, Pages 384-388Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2009.06.041
Keywords
Sealant; Sodium sulfur battery; Thermal expansion; Viscosity; Structure; Chemical compatibility
Funding
- NSFC [50730001]
- Chinese Science and Technology Ministry [2007BAA07B01, 2007CB209700]
- Science and Technology Commission of Shanghai Municipality [06DE12213, 07DE12004, 08DZ2210900]
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A novel Bi-doped borosilicate glass has been developed as sealant for sodium sulfur battery. The thermophysical characteristics like thermal expansion coefficient, glass transition and softening temperatures, viscosities and densities of the Bi-doped and undoped glasses are systematically studied. It is found that the thermal expansion match between the Bi-doped glasses and alpha-alumina/ beta-alumina is satisfactory. The Bi-doped glass has a viscosity around 10(5) Pa s in 800-850 degrees C range, which is suitable to allow a good bonding with the sealed parts. The FTIR analysis indicates that the substitution of Bi2O3 for SiO2 makes the glass network less rigid. Bi2O3 builds the glass network as [BiO6] unit. [BO4] unit enters the glass network and induces the overlapped vibrations of [BO4] unit and [SiO4] tetrahedron. The Bi-doped glass sealant exhibits superior chemical compatibility with alpha-alumina and beta-alumina. (C) 2009 Elsevier B. V. All rights reserved.
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